{"id":529,"date":"2026-04-22T09:35:48","date_gmt":"2026-04-22T00:35:48","guid":{"rendered":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/?p=529"},"modified":"2026-04-22T09:36:38","modified_gmt":"2026-04-22T00:36:38","slug":"%e3%80%90%e6%96%b0%e7%9d%80%e8%ab%96%e6%96%87%e3%80%91multicomponent-synthesis-of-%ce%b2-boryl-ketones-triggered-by-ketene-induced-metallate-rearrangement-of-alkenylboronic-esters","status":"publish","type":"post","link":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/archives\/529","title":{"rendered":"\u3010\u65b0\u7740\u8ad6\u6587\u3011Multicomponent Synthesis of \u03b2-Boryl Ketones Triggered by Ketene-Induced Metallate Rearrangement of Alkenylboronic Esters"},"content":{"rendered":"\n<p>Organic Letter \u8a8c\u306b<a href=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.orglett.6c00987\" target=\"_blank\" rel=\"noreferrer noopener\">\u30b1\u30c6\u30f3\u3092\u7528\u3044\u308b\u30a2\u30eb\u30b1\u30cb\u30eb\u30dc\u30e9\u30fc\u30c8\u306e\u30e1\u30bf\u30ec\u30fc\u30c8\u8ee2\u4f4d\u3092\u4f34\u3046\u591a\u6210\u5206\u9023\u7d50\u53cd\u5fdc\u306e\u8ad6\u6587<\/a>\u304c\u63b2\u8f09\u3055\u308c\u307e\u3057\u305f<\/p>\n\n\n\n<p>\u6700\u521d\u306e\u767a\u898b\u304b\u3089\u968f\u5206\u3068\u6642\u9593\u304c\u304b\u304b\u3063\u3066\u3057\u307e\u3044\u307e\u3057\u305f\u304c\u3001\u7686\u3055\u3093\u306e\u9811\u5f35\u308a\u306e\u304a\u304b\u3052\u3067\u5145\u5b9f\u3057\u305f\u5185\u5bb9\u306b\u306a\u3063\u305f\u3068\u601d\u3044\u307e\u3059\uff01<\/p>\n\n\n\n<p>\u68da\u5009\u3055\u3093\u3001\u53e4\u89d2\u3055\u3093\u3001\u7f8e\ufa11\u3055\u3093\u3001\u5742\u6771\u3055\u3093\u3001\u5c0f\u6a4b\u3055\u3093\u3000\u304a\u3081\u3067\u3068\u3046\u3054\u3056\u3044\u307e\u3059\uff01<\/p>\n\n\n\n<figure class=\"wp-block-image size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1000\" height=\"250\" src=\"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/WordPress\/wp-content\/uploads\/2026\/04\/ketene_HP.png\" alt=\"\" class=\"wp-image-524\" style=\"width:597px;height:auto\"\/><\/figure>\n\n\n\n<p><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Organic Letter \u8a8c\u306b\u30b1\u30c6\u30f3\u3092\u7528\u3044\u308b\u30a2\u30eb\u30b1\u30cb\u30eb\u30dc\u30e9\u30fc\u30c8\u306e\u30e1\u30bf\u30ec\u30fc\u30c8\u8ee2\u4f4d\u3092\u4f34\u3046\u591a\u6210\u5206\u9023\u7d50\u53cd\u5fdc\u306e\u8ad6\u6587\u304c\u63b2\u8f09\u3055\u308c\u307e\u3057\u305f \u6700\u521d\u306e\u767a\u898b\u304b\u3089\u968f\u5206\u3068\u6642\u9593\u304c\u304b\u304b\u3063\u3066\u3057\u307e\u3044\u307e\u3057\u305f\u304c\u3001\u7686\u3055\u3093\u306e\u9811\u5f35\u308a\u306e\u304a\u304b\u3052\u3067\u5145\u5b9f\u3057\u305f\u5185\u5bb9\u306b\u306a\u3063\u305f [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":524,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"sns_share_botton_hide":"","vkExUnit_sns_title":"","_vk_print_noindex":"","sitemap_hide":"","_veu_custom_css":"","veu_display_promotion_alert":"common","vkexunit_cta_each_option":"","footnotes":""},"categories":[4,6],"tags":[],"class_list":["post-529","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-news","category-publications"],"veu_head_title_object":{"title":"","add_site_title":""},"_links":{"self":[{"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/posts\/529","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/comments?post=529"}],"version-history":[{"count":1,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/posts\/529\/revisions"}],"predecessor-version":[{"id":530,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/posts\/529\/revisions\/530"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/media\/524"}],"wp:attachment":[{"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/media?parent=529"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/categories?post=529"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/tags?post=529"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}