{"id":97,"date":"2021-11-25T15:47:11","date_gmt":"2021-11-25T06:47:11","guid":{"rendered":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/WordPress\/?p=97"},"modified":"2021-11-25T16:00:29","modified_gmt":"2021-11-25T07:00:29","slug":"strain-release-difunctionalization-of-c-c-%cf%83-and-%cf%80-bonds-of-an-organoboron-ate-complex-through-12-metallate-rearrangement","status":"publish","type":"post","link":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/archives\/97","title":{"rendered":"Strain-Release Difunctionalization of C\u2013C \u03c3- and \u03c0-bonds of an Organoboron Ate-Complex through 1,2-Metallate Rearrangement"},"content":{"rendered":"\n<p>Haruki Mizoguchi,* Akira Sakakura*&nbsp;<br><em>Chem. Lett.<\/em><strong>2021<\/strong>,&nbsp;<em>50<\/em>&nbsp;(4), 792\u2013799. (Published online: January 13, 2021)&nbsp;<br><a href=\"https:\/\/doi.org\/10.1246\/cl.200926\">DOI: 10.1246\/cl.200926<img decoding=\"async\" src=\"http:\/\/www.cc.okayama-u.ac.jp\/~sakakura\/bioorgchem\/_src\/10724\/img20180629093542651479.png\" alt=\"LinkIcon\"><\/a><\/p>\n\n\n\n<figure class=\"wp-block-image size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/WordPress\/wp-content\/uploads\/2021\/07\/chemlett_highlight-1024x365.png\" alt=\"\" class=\"wp-image-98\" width=\"512\" height=\"183\" srcset=\"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/WordPress\/wp-content\/uploads\/2021\/07\/chemlett_highlight-1024x365.png 1024w, http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/WordPress\/wp-content\/uploads\/2021\/07\/chemlett_highlight-300x107.png 300w, http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/WordPress\/wp-content\/uploads\/2021\/07\/chemlett_highlight-768x274.png 768w, http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/WordPress\/wp-content\/uploads\/2021\/07\/chemlett_highlight-1536x547.png 1536w, http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/WordPress\/wp-content\/uploads\/2021\/07\/chemlett_highlight.png 1650w\" sizes=\"auto, (max-width: 512px) 100vw, 512px\" \/><\/figure>\n\n\n\n<p>This highlight review describes the recent development of an electrophile-triggered 1,2-metallate rearrangement of organoboronic ester ate-complex, which proceeds through 1,2-difunctionalization of carbon\u2013carbon \u03c3- and \u03c0-bonds, using strain energy as a driving force. Coupling reactions of small ring carbocyclic boronic esters, such as cyclopropyl-, bicyclo[1.1.0]butyl-, and cyclopropenyl-boronic ester, are summarized along with the proposed reaction mechanisms and representative examples.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Haruki Mizoguchi,* Akira Sakakura*&nbsp;Chem. Lett.2021,&nbsp;50&nbsp;(4), 792\u2013799. (Published online: January [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":98,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"vkexunit_cta_each_option":"","footnotes":""},"categories":[6],"tags":[],"class_list":["post-97","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-publications"],"_links":{"self":[{"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/posts\/97","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/comments?post=97"}],"version-history":[{"count":2,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/posts\/97\/revisions"}],"predecessor-version":[{"id":269,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/posts\/97\/revisions\/269"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/media\/98"}],"wp:attachment":[{"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/media?parent=97"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/categories?post=97"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/bioorgchem\/wp-json\/wp\/v2\/tags?post=97"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}