{"id":5620,"date":"2021-11-29T18:55:03","date_gmt":"2021-11-29T09:55:03","guid":{"rendered":"http:\/\/achem.okayama-u.ac.jp\/interface\/master\/?page_id=5620"},"modified":"2024-10-06T23:05:52","modified_gmt":"2024-10-06T14:05:52","slug":"ionic-liquids","status":"publish","type":"page","link":"http:\/\/achem.okayama-u.ac.jp\/interface\/en\/en-research\/ionic-liquids\/","title":{"rendered":"Ionic Liquids"},"content":{"rendered":"<p><img decoding=\"async\" loading=\"lazy\" class=\"size-full wp-image-5454 aligncenter\" src=\"http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/ionic-liquids.png\" alt=\"\u30a4\u30aa\u30f3\u6db2\u4f53\u6750\u6599\" width=\"700\" height=\"350\" srcset=\"http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/ionic-liquids.png 700w, http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/ionic-liquids-300x150.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p style=\"text-align: left;\">We develop functional materials showing ionic liquid properties such as tunable physicochemical properties, ionic conductivity, carbon dioxide absorption properties, and thermal resistance.<\/p>\n<h2><a id=\"i01\"><\/a>Ionic Liquid-based Coating Agent<\/h2>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"alignright size-full wp-image-5456\" src=\"http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/i01.png\" alt=\"\u30a4\u30aa\u30f3\u6db2\u4f53\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u5264\u306e\u958b\u767a\" width=\"400\" height=\"320\" srcset=\"http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/i01.png 400w, http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/i01-300x240.png 300w\" sizes=\"(max-width: 400px) 100vw, 400px\" \/>Ionic liquid is a general term for organic salts that are liquid states at room temperature, and the hydrophilic and hydrophobic properties can be controlled by the constituent ions. We have succeeded in synthesizing silane coupling agents with ionic liquid properties (ionic liquid silane coupling agents, ILSCs and control the wettability of material surface by ILSCs coating. We expect that ILSCs can be applied to antistatic agents and surface coating materials.<\/p>\n<h2><a id=\"i02\"><\/a>Clickable Ionic Liquid Monomers<\/h2>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"size-full wp-image-5457 alignright\" src=\"http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/i02.png\" alt=\"\u9ad8\u30a4\u30aa\u30f3\u4f1d\u5c0e\u6027\u3092\u793a\u3059\u9ad8\u5206\u5b50\u30a4\u30aa\u30f3\u6db2\u4f53\u306e\u958b\u767a\" width=\"400\" height=\"360\" srcset=\"http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/i02.png 400w, http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/i02-300x270.png 300w\" sizes=\"(max-width: 400px) 100vw, 400px\" \/>Polymers with an ionic liquid moiety in the main chain are called main-chain poly(ionic liquid)s. These materials are expected to be used in solid electrolytes and sensors due to their excellent ionic conductivity. However, little progress has been made in their development due to the complicated synthesis method.<br \/>\n\u3000We have developed click-reactive ionic liquid monomers. The click reactions using these monomers have made it possible to produce main-chain poly(ionic liquid)s in one-step reaction with only heating. The resultant polymers exhibited excellent ionic conductivity on the order of 10-5 S\/cm at 30\u00b0C. We are addressing to control the physicochemical properties of main-chain poly(ionic liquid)s by precisely designing monomers.<\/p>\n<ul>\n<li>References<br \/>\nR. Hirai <em>et al., ACS Omega<\/em> <strong>6(15)<\/strong>, 10030\u201310038 (2021)<br \/>\nR. Hirai <em>et al., RSV Adv<\/em>., <strong>10<\/strong>, 37743\u201337748 (2020)<\/li>\n<\/ul>\n<h2><a id=\"i03\"><\/a>Tough Poly(ionic liquid)s-based Ion Gels<\/h2>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"alignright size-full wp-image-5458\" src=\"http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/i03.png\" alt=\"\u9ad8\u5f37\u5ea6\u30a4\u30aa\u30f3\u30b2\u30eb\u306e\u958b\u767a\" width=\"400\" height=\"360\" srcset=\"http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/i03.png 400w, http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2021\/11\/i03-300x270.png 300w\" sizes=\"(max-width: 400px) 100vw, 400px\" \/>Ion gels are composed of a three-dimensional cross-linked polymer network and an ionic liquid as a solvent. Since ion-gels exhibit non-volatility, carbon dioxide absorption capacity, and high ionic conductivity, they are expected to be used as high-performance carbon dioxide separation membranes and actuators that can operate in harsh environments. However, the mechanical strength of ion-gels is generally low. It is therefore necessary to increase their strength for practical use.<br \/>\n\u3000We have found that adding a small amount of nanomaterials such as silica particles to an ion-gel consisting of a cross-linked network of poly(ionic liquid)s increases the toughness of the ion-gel by forming a double network (DN) structure. In addition, the ion-gels exhibit properties that are not seen in conventional hydrogels, such as high heat resistance and water resistance. We study the toughening mechanism of the ion-gels, and to apply iongels to carbon dioxide separation membranes and soft actuators.<\/p>\n<ul>\n<li>References<br \/>\nT. Watanabe <em>et al., Soft Matter<\/em> <strong>16<\/strong>, 1572\u20131581 (2020)<br \/>\nT. Watanabe <em>et al.<\/em>, <em>Soft Matter<\/em> <strong>19<\/strong>, 2745\u20132754 (2023)<br \/>\nY. Mizutani <em>et al.<\/em>, <em>Soft matter<\/em> <strong>20<\/strong>, 1611\u20131619 (2024)<\/li>\n<\/ul>\n<h2>Poly(ionic liquid)-based Vitrimer<\/h2>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"wp-image-6212 alignright\" style=\"font-size: 1rem;\" src=\"http:\/\/achem.okayama-u.ac.jp\/interface\/master\/wp-content\/uploads\/2024\/10\/795316b92fc766b0181f6fef074f03fa.png\" alt=\"\" width=\"418\" height=\"451\">Cross-linked polymers, such as rubber bands and superabsorbent polymers, have their structures permanently fixed by covalent cross-links, making secondary processing and recycling difficult. Recently, attention has been drawn to a new type of cross-linked polymer called &#8216;Vitrimers,&#8217; which utilize &#8216;permanent dynamic covalent bonds&#8217; that allow the cross-linked structure to rearrange in response to environmental stimuli such as heat. Vitrimers hold promise for applications in durable, easily recyclable materials and self-healing materials that respond to heat or light.<br \/>\n&nbsp; &nbsp; We study on the development of vitrimers with excellent ionic conductivity, based on click-reactive ionic liquid monomers.<\/p>\n<ul>\n<li>References<br \/>\nR. Hirai <em>et al., ACS Omega<\/em> <strong>6(15)<\/strong>, 10030\u201310038 (2021)<br \/>\nR. Hirai <em>et al., RSC Adv<\/em>., <strong>10<\/strong>, 37743\u201337748 (2020)<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>We develop functional materials showing ionic liquid properties such as tunable physicochemical properties, io [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":5618,"menu_order":13,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":"","_locale":"en_US","_original_post":"http:\/\/achem.okayama-u.ac.jp\/interface\/master\/?page_id=5410","_expiration-date-status":"","_expiration-date":0,"_expiration-date-type":"","_expiration-date-categories":[],"_expiration-date-options":[]},"_links":{"self":[{"href":"http:\/\/achem.okayama-u.ac.jp\/interface\/wp-json\/wp\/v2\/pages\/5620"}],"collection":[{"href":"http:\/\/achem.okayama-u.ac.jp\/interface\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/achem.okayama-u.ac.jp\/interface\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/interface\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/interface\/wp-json\/wp\/v2\/comments?post=5620"}],"version-history":[{"count":7,"href":"http:\/\/achem.okayama-u.ac.jp\/interface\/wp-json\/wp\/v2\/pages\/5620\/revisions"}],"predecessor-version":[{"id":6220,"href":"http:\/\/achem.okayama-u.ac.jp\/interface\/wp-json\/wp\/v2\/pages\/5620\/revisions\/6220"}],"up":[{"embeddable":true,"href":"http:\/\/achem.okayama-u.ac.jp\/interface\/wp-json\/wp\/v2\/pages\/5618"}],"wp:attachment":[{"href":"http:\/\/achem.okayama-u.ac.jp\/interface\/wp-json\/wp\/v2\/media?parent=5620"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}